Inside the Secret Lives of Angelina Jolie and Brad Pitt’s ChildrenHow The Jolie-Pitt Kids Are Dealing With Their Parents Split Hollywood was shook after news of Jennifer Aniston and Brad Pitt’s separation was leaked in 2005. What was even more unbelievable was the fact that Brad showed up on magazine covers with Angelina Jolie the same year. It was the relationship that sparked the ‘team Jenn’ vs ‘team Angelina’ debate, and it was the biggest scandal of the decade. But, as time went on, the world got to see just how awesome Brangelina truly was. We watched them adopt kids, have their biological babies, and it really seemed like they were going to break the usual Hollywood couple mold.